Analysis of the difference between the model and real value of electricity consumption

Hlavním cílem této práce je ukázat význam typových diagramů dodávek, určit jejich poplatnost k dnešní době, identifikovat slabé stránky a doporučit možné návrhy pro zpřesnění mechanismu TDD. Nejdříve bude vysvětleno a popsáno fungování trhu s elektřinou, se zaměřením především na spotřebu elektřiny a chování koncových odběratelů, a také nastíněn možný budoucí vývoj v této oblasti. Dále bude popsán současný způsob měření spotřeby elektřiny, nastíněn budoucí vývoj a možný dopad nástupu nových technologií. Právě v současném modelu měření a vyhodnocování spotřeby odběratelů je uplatňována metodika TDD pro neprůběhově měřené zákazníky. Tato metodika bude podrobně analyzována na konkrétním příkladu vyhodnocení odchylky u jednoho spotřebitele. Na závěr bude vyhodnocena funkce a přesnost systému TDD a doporučeny některé návrhy na její zlepšení.The main aim of this Diploma thesis is to show the importance of load profiles, their applications in nowadays conditions of energetics, identify weaknesses and recommend some proposals to achieve more accuracy of load profiles. First of all it is necessary to explained and described electricity market, connections between market participants with focus on electricity consumption and consumer behavior. Also will be indicate future development in electricity consumption. Then will be describe and explained current state of measuring electricity consumption, future development and expected changes due to new technologies like smart metering and smart grids. Under current conditions load profiles are used to settlement of differences between the actual and allocated consumption values for the type C metering. After that will be system of load profiles analysis on specific example of consumption evaluation by one electricity consumer. Finally will be evaluated function and accuracy of load profiles and given some suggestion of improve proposal

Corrigin area land resources survey

This land resource survey of the Corrigin area covers some 1.8 million hectares of the central wheatbelt over the shires of Beverley, Brookton, Bruce Rock, Corrigin, Cuballing, Cunderdin, Dumbleyung, Kellerberrin, Kondinin, Kulin, Lake Grace, Merredin, Narembeen, Narrogin, Pingelly, Quairading, Tammin, Wandering and Wickepin. The survey is part of a regional scale soil-landscape mapping program designed to deliver seamless soil information for the agricultural area of south western Australia. The information provided will assist planners, researchers and land managers make decisions affecting sustainable land use and is designed for use at regional and catchment scales. This report and accompanying CD-ROM summarizes primary and interpreted information on the soil-landscapes of the Corrigin area. The report outlines the main degradation issues and supplies background information on climate, native vegetation and geology. An important additional outcome of the survey is a new theory on soil formation that has wide-ranging ramifications for agriculture, soil science, botany and geomorphology. Thirty-six soil-landscape systems, together with their component sub-systems and phases were recognised, mapped and described during the survey. This information, together with unmapped soil types and land qualities, is provided in the CD-ROM. The CD also showcases the main soils, provides geo-referenced soil pit and auger descriptions, maps of soil-landscapes and maps of selected degradation hazards

Liquid/Liquid Extraction Kinetics of Eu(III) and Am(III) by Extractants Designed for the Industrial Reprocessing of Nuclear Wastes

Results about the kinetics of extraction of Eu(III) and Am(III) by extractants designed for the industrial reprocessing of nuclear wastes are reported. They were obtained using the rotating membrane cell (RMC) technique. Extraction and stripping kinetic rate constants were determined for various compositions of the aqueous and organic phases. The transfer was studied at liquid/liquid interfaces between an aqueous nitric acid solution and an organic solvent containing the diglycolamide extractant molecule N,N,N′,N′-tetra-n-octyl-diglycolamide (TODGA) or a mixture of the bipyridine molecule CyMe4BTBP with TODGA (the latter being used as a phase-transfer catalyst), dissolved in an aliphatic diluent. In some experiments, an aqueous ligand (a sulfonated bis triazinyl pyridine, SO3-Ph-BTP, or a PyTri-diol) was added to the aqueous phase as a stripping agent. The diffusion coefficients of Eu(III) and Am(III), which are key in the analysis of the kinetic data, were measured using the RMC and the closed capillary technique. Whenever possible, mechanisms are proposed to interpret the experimental results

One-pot Selective Formylation and Claisen Rearrangement on Calix[4]arenes

A versatile synthon with formyl and allyl groups at the upper rim of calix[4]arene has been synthesized in two steps. Selective formylation of 25,27-diallyloxy-26,28-dihydroxycalix[4]arene, along with the Claisen rearrangement of the allyl groups, was achieved by reaction with hexamethylenetetraamine (hexamine) in glacial acetic acid. A control reaction of the dipropyl analogue shows that the selective formylation takes place independently of the Claisen rearrangement. The crystal structure of the dimethylacetal derivative of 5,17-diformyl-11,23-diallylcalix[4]arene is reported

Wetenschappers en veldwerkers in Gelderland bespreken gevolgen klimaatverandering

Waterschappen, provincies, waterbedrijven en andere partijen werken vaak samen aan ruimtelijke plannen voor de inrichting van het landelijk gebied. De optimalisering van de waterhuishouding voor landbouw en natuur speelt in zulke plannen meestal een cruciale rol. De vraag is echter of daarbij voldoende rekening wordt gehouden met de mogelijke gevolgen van de veranderingen in het klimaat. Deze worden vooral onderzocht door wetenschappers op universiteiten en kennisinstituten, die zich doorgaans weinig bekommeren om gebiedsprocessen. In de provincie Gelderland zijn wetenschappers en mensen uit het veld onlangs samengekomen om de gevolgen van het warmer en grilliger wordende klimaat in kaart te brengen en na te denken over adaptieve maatregelen voor twee gebieden: Blauwe Bron en Baakse Beek

Nucleophilic Functionalization of the Calix[6]arene Para- and Meta-Position via p‑Bromodienone Route

It is here demonstrated that the p-bromodienone route, previously reported for calix[4]arenes, is also effective for the functionalization of the calix[6]arene macrocycle. Thus, alcoholic O-nucleophiles can be introduced at the calix[6]arene exo rim. In addition, the reaction of a calix[6]arene p-bromodienone derivative with an actived aromatic substrate, such as resorcinol, led to the first example of a meta-functionalized, inherently chiral calix[6]arene derivativ

Adaptive Radiation in Mediterranean Cistus (Cistaceae)

lineage consists of 12 species primarily distributed in Mediterranean habitats and is herein subject to analysis. lineages), which display asymmetric characteristics: number of species (2 vs. 10), leaf morphologies (linear vs. linear to ovate), floral characteristics (small, three-sepalled vs. small to large, three- or five-sepalled flowers) and ecological attributes (low-land vs. low-land to mountain environments). A positive phenotype-environment correlation has been detected by historical reconstructions of morphological traits (leaf shape, leaf labdanum content and leaf pubescence). Ecological evidence indicates that modifications of leaf shape and size, coupled with differences in labdanum secretion and pubescence density, appear to be related to success of new species in different Mediterranean habitats.

Rapid characterisation of vegetation structure to predict refugia and climate change impacts across a global biodiversity hotspot

Identification of refugia is an increasingly important adaptation strategy in conservation planning under rapid anthropogenic climate change. Granite outcrops (GOs) provide extraordinary diversity, including a wide range of taxa, vegetation types and habitats in the Southwest Australian Floristic Region (SWAFR). However, poor characterization of GOs limits the capacity of conservation planning for refugia under climate change. A novel means for the rapid identification of potential refugia is presented, based on the assessment of local-scale environment and vegetation structure in a wider region. This approach was tested on GOs across the SWAFR. Airborne discrete return Light Detection And Ranging (LiDAR) data and Red Green and Blue (RGB) imagery were acquired. Vertical vegetation profiles were used to derive 54 structural classes. Structural vegetation types were described in three areas for supervised classification of a further 13 GOs across the region.Habitat descriptions based on 494 vegetation plots on and around these GOs were used to quantify relationships between environmental variables, ground cover and canopy height. The vegetation surrounding GOs is strongly related to structural vegetation types (Kappa = 0.8) and to its spatial context. Water gaining sites around GOs are characterized by taller and denser vegetation in all areas. The strong relationship between rainfall, soil-depth, and vegetation structure (R2 of 0.8–0.9) allowed comparisons of vegetation structure between current and future climate. Significant shifts in vegetation structural types were predicted and mapped for future climates. Water gaining areas below granite outcrops were identified as important putative refugia. A reduction in rainfall may be offset by the occurrence of deeper soil elsewhere on the outcrop. However, climate change interactions with fire and water table declines may render our conclusions conservative. The LiDAR-based mapping approach presented enables the integration of site-based biotic assessment with structural vegetation types for the rapid delineation and prioritization of key refugia